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| 內容簡介: |
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本书以电化学方法分类,介绍了平衡电化学、电极过程动力学、循环伏安法、流体电化学等电化学基础知识,同时还用实例介绍了电化学技术的应用,如分析电化学,碳电化学以及电化学在储能和产能方面的应用等。本书介绍电化学的视野开阔,不仅为读者提供了一些关键的电化学原理解释,而且列举了很多有趣的技术应用,且以英文写作,较适宜作为高校电化学专业高年级本科生和研究生的双语教材,也可作为技术人员的参考书。
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| 目錄:
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1 Equilibrium Electrochemistry
1.1 Chemical Equilibrium
1.2 An Introduction to Electrochemical Equilibrium
1.3 Electron Transfer at the Solution | Electrode Interface
1.4 The Nernst Equation and Electrode | Solution
Interfaces
1.4.1 One Phase to Another
1.5 Reference Electrodes
1.6 Standard Electrode Potentials
1.7 Formal Potentials
References
2 Electrode Kinetics
2.1 Introduction to Dynamic Electrochemistry
2.2 Experimental Arrangement
2.3 Electron Transfer and Energy Levels
2.4 Electrode Kinetics
2.5 The Tafel Law
2.6 Introduction to Marcus Theory
References
3 Cyclic Voltammetry
3.1 Introduction
3.2 Diffusion
3.2.1 The Nernst Diffusion Layer
3.3 Migration
3.4 Electrode-Solution Interface
3.5 Electrode Kinetics
3.6 Reaction Mechanisms
3.7 pH Effects
3.8 Voltammetry at Microelectrodes
3.9 Chronoamperometric Experiments: Determining the
Electro-catalytic Rate Constant
3.10 EC′ Mechanism at a Microdisc Electrode
3.11 ECE Mechanism at a Microdisc Electrode
3.12 Effect of Temperature on Steady-state Currents at a
Microdisc
3.13 Properties of Microelectrodes
3.14 Applications of Microelectrodes
3.15 Microelectrode Arrays
3.16 Graphitic and Related Electrode Surfaces
3.17 Voltammetry at Heterogeneous Surfaces
3.18 Thin Layer Effects from Modifying Electrodes
References
4 Hydrodynamic Techniques
4.1 Introduction to Convection
4.2 Rotating Disc Systems
4.3 Channel and Tubular Electrodes
4.4 High Speed Channel Electrode
4.5 Hydrodynamic Electrodes Based on Impinging Jets
References
5 Electroanalysis
5.1 Introduction to Electroanalysis
5.2 Square Wave Voltammetry
5.3 Stripping Voltammetry
5.4 Sono-electroanalysis
5.5 Screen Printed Sensors
5.6 Bismuth Modified Electrodes
5.7 Relevant Analytical Parameters
References
6 Carbon Electrochemistry
6.1 Introduction
6.2 Carbon Nanotubes
6.3 Graphene Electrochemistry
6.3.1 Electrochemistry of heterogeneous graphitic
surfaces
6.3.2 Fundamental electrochemistry of graphene
6.3.3 Graphene as a heterogeneous electrode surface
6.3.4 Effect of surfactants on the electrochemistry
of graphene
6.3.5 Metallic impurities on the electrochemistry of
graphene
6.3.6 Direct electro-catalysis
6.3.7 Graphene OxideGO
References
7 Energy Storage and Generation
7.1 Introduction
7.2 Super- and Ultra-Capacitors
7.3 Testing Super- and Ultra-Capacitors
7.4 Cycle Life
7.5 Graphene Based Supercapacitors
7.6 Hybrid Super-or Ultra-Capacitors
7.6.1 Noble Metal Oxides
7.6.2 Asymmetrical Supercapacitors
7.7 Fuel Cells
7.7.1 Graphene Based Fuel Cells
7.7.2 Microbial Bio-fuel Cells
7.7.3 Enzymatic Bio-fuel Cells
7.8 Batteries Li-ion Batteries
References
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